The coordination and polymerisation of cyclic 1,3-dienes by gold(I) cations.
نویسندگان
چکیده
Cyclopentadiene and 1,3-cyclohexadiene are readily polymerised by [LAu][X]. With specific ancillary ligands polymerisation was suppressed and a molecular species involving an Au(I) cation η(2)-bonding CpH was isolated and whose structure was probed in both the solid state and in solution.
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عنوان ژورنال:
- Chemical communications
دوره 48 7 شماره
صفحات -
تاریخ انتشار 2012